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Рассчитать значение ПДО/ПДП
Наименование компонента
| Номер в Госреестре СО | разряд | Пределы допускаемых отклонений (ПДО) | Пределы допускаемых погрешностей (ПДП) | ||||
|---|---|---|---|---|---|---|---|
| ГСО 12329-2023 | 0 | абс | % мол | абс | % мол | ||
| отн | % | отн | % | ||||
| ГСО 12330-2023 | 1 | абс | % мол | абс | % мол | ||
| отн | % | отн | % | ||||
| ГСО 12331-2023 | 2 | абс | % мол | абс | % мол | ||
| отн | % | отн | % | ||||
Стандартный образец представляет собой искусственную газовую смесь исходных веществ. Смесь находится под давлением (0,05 – 15) МПа, в баллонах вместимостью (0,5 – 50) дм3 с вентилями в соответствии с требованиями ГОСТ Р 8.776-2011 «ГСИ. Стандартные образцы состава газовых смесей. Общие метрологические и технические требования». СО запрещается изготавливать во взрывопожароопасных концентрациях, с сочетанием компонентов, способных вступать друг с другом в химические реакции, с нестабильными компонентами, компонентами способными к полимеризации в условиях использования, хранения и транспортирования в соответствии с ГОСТ Р 8.776-2011. Показатели пожаровзрывоопасности веществ и методы их определения указаны в ГОСТ 12.1.044-89, ГОСТ 31610.20-1-2020 (ISO/IEC 80079-20-1:2017).
| № ГСО | СО состава искусственной газовой смеси | Индекс СО | Разряд | Срок годности, мес. |
Описание типа СО |
| 12329-2023 | на основе постоянных и инертных газов | ПИ-М-0 | 0 | 24 | Описание типа СО |
| 12330-2023 | на основе постоянных и инертных газов | ПИ-М-1 | 1 | 24 | Описание типа СО |
| 12331-2023 | на основе постоянных и инертных газов | ПИ-М-2 | 2 | 24 | Описание типа СО |
ГСО 12329-2023
Стандартный образец состава искусственной газовой смеси на основе постоянных и инертных газов (ПИ-М-0)
| Определяемый компонент | Интервал допускаемых (номинальных) аттестованных значений молярной доли, % | Допускаемые значения относительной расширенной неопределенности (U0)* при k = 2 и Р = 0,95, % |
|
воздух [air]
аргон [Ar]
тетрафторэтилен [C2F4]
гексафторэтан (R-116) [C2F6]
этилен [C2H4]
этан [C2H6]
пропан [C3H8]
тетрафторметан (R-14) [CF4]
метан [CH4]
монооксид углерода [CO]
диоксид углерода [CO2]
дейтерий [D2]
водород [H2]
гелий [He]
криптон [Kr]
азот [N2]
оксид диазота (закись азота) [N2O]
неон [Ne]
кислород [O2]
гексафторид серы [SF6]
ксенон [Xe]
|
от 1·10-5 до 5·10-5 вкл. | 5 |
| св. 5·10-5 до 1·10-4 вкл. | 2,5 | |
| св. 1·10-4 до 1·10-3 вкл. | 2,0 | |
| св. 1·10-3 до 1·10-2 вкл. | 1,25 | |
| св. 1·10-2 до 0,1 вкл. | 1,0 | |
| св. 0,1 до 1 вкл. | 0,5 | |
| св. 1 до 10 вкл. | 0,4 | |
| св. 10 до 20 вкл. | 0,3 | |
| св. 20 до 50 вкл. | 0,15 | |
| св. 50 до 70 вкл. | 0,10 | |
| св. 70 до 90 вкл. | 0,05 | |
| св. 90 до 99 вкл. | 0,025 | |
| св. 99 до 99,9 | 0,005 | |
|
н-бутан [C4H10]
|
от 1·10-5 до 5·10-5 вкл. | 5 |
| св. 5·10-5 до 1·10-4 вкл. | 2,5 | |
| св. 1·10-4 до 1·10-3 вкл. | 2,0 | |
| св. 1·10-3 до 1·10-2 вкл. | 1,25 | |
| св. 1·10-2 до 0,1 вкл. | 1,0 | |
| св. 0,1 до 1 вкл. | 0,5 | |
| св. 1 до 10 вкл. | 0,4 | |
| св. 10 до 20 вкл. | 0,3 | |
| св. 20 до 50 вкл. | 0,15 | |
| св. 50 до 70 вкл. | 0,10 | |
| св. 70 до 80 | 0,05 | |
|
н-пентан [C5H12]
|
от 1·10-5 до 5·10-5 вкл. | 5 |
| св. 5·10-5 до 1·10-4 вкл. | 2,5 | |
| св. 1·10-4 до 1·10-3 вкл. | 2,0 | |
| св. 1·10-3 до 1·10-2 вкл. | 1,25 | |
| св. 1·10-2 до 0,1 вкл. | 1,0 | |
| св. 0,1 до 1 вкл. | 0,5 | |
| св. 1 до 10 вкл. | 0,4 | |
| св. 10 до 20 вкл. | 0,3 | |
| св. 20 до 30 | 0,15 | |
|
ацетилен [C2H2]
|
от 1·10-5 до 5·10-5 вкл. | 5 |
| св. 5·10-5 до 1·10-4 вкл. | 2,5 | |
| св. 1·10-4 до 1·10-3 вкл. | 2,0 | |
| св. 1·10-3 до 1·10-2 вкл. | 1,25 | |
| св. 1·10-2 до 0,1 вкл. | 1,0 | |
| св. 0,1 до 1 вкл. | 0,5 | |
| св. 1 до 10 вкл. | 0,4 | |
| св. 10 до 12,5 | 0,3 | |
|
н-гексан [C6H14]
|
от 1·10-5 до 5·10-5 вкл. | 5 |
| св. 5·10-5 до 1·10-4 вкл. | 2,5 | |
| св. 1·10-4 до 1·10-3 вкл. | 2,0 | |
| св. 1·10-3 до 1·10-2 вкл. | 1,25 | |
| св. 1·10-2 до 0,1 вкл. | 1,0 | |
| св. 0,1 до 1 вкл. | 0,5 | |
| св. 1 до 7 | 0,4 | |
|
тетрахлорметан (R-10) [CCl4]
|
от 1·10-5 до 5·10-5 вкл. | 5 |
| св. 5·10-5 до 1·10-4 вкл. | 2,5 | |
| св. 1·10-4 до 1·10-3 вкл. | 2,0 | |
| св. 1·10-3 до 1·10-2 вкл. | 1,25 | |
| св. 1·10-2 до 0,1 вкл. | 1,0 | |
| св. 0,1 до 1 вкл. | 0,5 | |
| св. 1 до 5 | 0,4 | |
|
вода [H2O]
|
от 5·10-5 до 1·10-4 вкл. | 2,5 |
| св. 1·10-4 до 1·10-3 вкл. | 2,0 | |
| св. 1·10-3 до 1·10-2 вкл. | 1,25 | |
| св. 1·10-2 до 0,1 вкл. | 1,0 | |
| св. 0,1 до 0,5 | 1,0 |
* – численно равны границам относительной погрешности при доверительной вероятности P=0,95.
| Интервал номинальных значений молярной доли определяемых компонентов СО, % | Пределы допускаемого относительного отклонения ±Д, % |
| от 1·10-5 до 5·10-5 вкл. | 100 |
| св. 5·10-5 до 1·10-4 вкл. | 50 |
| св. 1·10-4 до 1·10-3 вкл. | 30 |
| св. 1·10-3 до 1·10-2 вкл. | 20 |
| св. 1·10-2 до 0,1 вкл. | 10 |
| св. 0,1 до 1 вкл. | 5 |
| св. 1 до 10 вкл. | 4 |
| св. 10 до 70 вкл. | 2 |
| св. 70 до 90 вкл. | 1 |
| св. 90 до 99 вкл. | 0,5 |
| св. 99 до 99,9 | 0,1 |
ГСО 12330-2023
Стандартный образец состава искусственной газовой смеси на основе постоянных и инертных газов (ПИ-М-1)
| Определяемый компонент | Интервал допускаемых (номинальных) аттестованных значений молярной доли, % | Допускаемые значения относительной расширенной неопределенности (U0)* при k = 2 и Р = 0,95, % |
|
воздух [air]
аргон [Ar]
тетрафторэтилен [C2F4]
гексафторэтан (R-116) [C2F6]
этилен [C2H4]
этан [C2H6]
пропан [C3H8]
тетрафторметан (R-14) [CF4]
метан [CH4]
монооксид углерода [CO]
диоксид углерода [CO2]
дейтерий [D2]
водород [H2]
гелий [He]
криптон [Kr]
азот [N2]
оксид диазота (закись азота) [N2O]
неон [Ne]
кислород [O2]
гексафторид серы [SF6]
ксенон [Xe]
|
от 1·10-5 до 5·10-5 вкл. | 10 |
| св. 5·10-5 до 1·10-4 вкл. | 5 | |
| св. 1·10-4 до 1·10-3 вкл. | 4 | |
| св. 1·10-3 до 1·10-2 вкл. | 2,5 | |
| св. 1·10-2 до 0,1 вкл. | 2,0 | |
| св. 0,1 до 1 вкл. | 1,25 | |
| св. 1 до 10 вкл. | 1,0 | |
| св. 10 до 20 вкл. | 0,6 | |
| св. 20 до 50 вкл. | 0,3 | |
| св. 50 до 70 вкл. | 0,20 | |
| св. 70 до 90 вкл. | 0,10 | |
| св. 90 до 99 вкл. | 0,05 | |
| св. 99 до 99,9 | 0,010 | |
|
н-бутан [C4H10]
|
от 1·10-5 до 5·10-5 вкл. | 10 |
| св. 5·10-5 до 1·10-4 вкл. | 5 | |
| св. 1·10-4 до 1·10-3 вкл. | 4 | |
| св. 1·10-3 до 1·10-2 вкл. | 2,5 | |
| св. 1·10-2 до 0,1 вкл. | 2,0 | |
| св. 0,1 до 1 вкл. | 1,25 | |
| св. 1 до 10 вкл. | 1,0 | |
| св. 10 до 20 вкл. | 0,6 | |
| св. 20 до 50 вкл. | 0,3 | |
| св. 50 до 70 вкл. | 0,20 | |
| св. 70 до 80 | 0,10 | |
|
н-пентан [C5H12]
|
от 1·10-5 до 5·10-5 вкл. | 10 |
| св. 5·10-5 до 1·10-4 вкл. | 5 | |
| св. 1·10-4 до 1·10-3 вкл. | 4 | |
| св. 1·10-3 до 1·10-2 вкл. | 2,5 | |
| св. 1·10-2 до 0,1 вкл. | 2,0 | |
| св. 0,1 до 1 вкл. | 1,25 | |
| св. 1 до 10 вкл. | 1,0 | |
| св. 10 до 20 вкл. | 0,6 | |
| св. 20 до 30 | 0,3 | |
|
ацетилен [C2H2]
|
от 1·10-5 до 5·10-5 вкл. | 10 |
| св. 5·10-5 до 1·10-4 вкл. | 5 | |
| св. 1·10-4 до 1·10-3 вкл. | 4 | |
| св. 1·10-3 до 1·10-2 вкл. | 2,5 | |
| св. 1·10-2 до 0,1 вкл. | 2,0 | |
| св. 0,1 до 1 вкл. | 1,25 | |
| св. 1 до 10 вкл. | 1,0 | |
| св. 10 до 12,5 | 0,6 | |
|
н-гексан [C6H14]
|
от 1·10-5 до 5·10-5 вкл. | 10 |
| св. 5·10-5 до 1·10-4 вкл. | 5 | |
| св. 1·10-4 до 1·10-3 вкл. | 4 | |
| св. 1·10-3 до 1·10-2 вкл. | 2,5 | |
| св. 1·10-2 до 0,1 вкл. | 2,0 | |
| св. 0,1 до 1 вкл. | 1,25 | |
| св. 1 до 7 | 1,0 | |
|
тетрахлорметан (R-10) [CCl4]
|
от 1·10-5 до 5·10-5 вкл. | 10 |
| св. 5·10-5 до 1·10-4 вкл. | 5 | |
| св. 1·10-4 до 1·10-3 вкл. | 4 | |
| св. 1·10-3 до 1·10-2 вкл. | 2,5 | |
| св. 1·10-2 до 0,1 вкл. | 2,0 | |
| св. 0,1 до 1 вкл. | 1,25 | |
| св. 1 до 5 | 1,0 | |
|
вода [H2O]
|
от 5·10-5 до 1·10-4 вкл. | 5 |
| св. 1·10-4 до 1·10-3 вкл. | 4 | |
| св. 1·10-3 до 1·10-2 вкл. | 2,5 | |
| св. 1·10-2 до 0,1 вкл. | 2,0 | |
| св. 0,1 до 0,5 | 2,0 |
* – численно равны границам относительной погрешности при доверительной вероятности P=0,95.
| Интервал номинальных значений молярной доли определяемых компонентов СО, % | Пределы допускаемого относительного отклонения ±Д, % |
| от 1·10-5 до 5·10-5 вкл. | 100 |
| св. 5·10-5 до 1·10-4 вкл. | 50 |
| св. 1·10-4 до 1·10-3 вкл. | 30 |
| св. 1·10-3 до 1·10-2 вкл. | 20 |
| св. 1·10-2 до 0,1 вкл. | 15 |
| св. 0,1 до 1 вкл. | 7 |
| св. 1 до 10 вкл. | 5 |
| св. 10 до 20 вкл. | 3 |
| св. 20 до 90 вкл. | 2 |
| св. 90 до 99 вкл. | 0,5 |
| св. 99 до 99,9 | 0,1 |
ГСО 12331-2023
Стандартный образец состава искусственной газовой смеси на основе постоянных и инертных газов (ПИ-М-2)
| Определяемый компонент | Интервал допускаемых (номинальных) аттестованных значений молярной доли, % | Допускаемые значения относительной расширенной неопределенности (U0)* при k = 2 и Р = 0,95, % |
|
воздух [air]
аргон [Ar]
тетрафторэтилен [C2F4]
гексафторэтан (R-116) [C2F6]
этилен [C2H4]
этан [C2H6]
пропан [C3H8]
тетрафторметан (R-14) [CF4]
метан [CH4]
монооксид углерода [CO]
диоксид углерода [CO2]
дейтерий [D2]
водород [H2]
гелий [He]
криптон [Kr]
азот [N2]
оксид диазота (закись азота) [N2O]
неон [Ne]
кислород [O2]
гексафторид серы [SF6]
ксенон [Xe]
|
от 1·10-5 до 5·10-5 вкл. | 15 |
| св. 5·10-5 до 1·10-4 вкл. | 10 | |
| св. 1·10-4 до 1·10-3 вкл. | 7 | |
| св. 1·10-3 до 1·10-2 вкл. | 5 | |
| св. 1·10-2 до 0,1 вкл. | 4 | |
| св. 0,1 до 1 вкл. | 3 | |
| св. 1 до 10 вкл. | 2,5 | |
| св. 10 до 20 вкл. | 2,0 | |
| св. 20 до 50 вкл. | 1,0 | |
| св. 50 до 70 вкл. | 0,5 | |
| св. 70 до 90 вкл. | 0,25 | |
| св. 90 до 99 вкл. | 0,10 | |
| св. 99 до 99,9 | 0,03 | |
|
н-бутан [C4H10]
|
от 1·10-5 до 5·10-5 вкл. | 15 |
| св. 5·10-5 до 1·10-4 вкл. | 10 | |
| св. 1·10-4 до 1·10-3 вкл. | 7 | |
| св. 1·10-3 до 1·10-2 вкл. | 5 | |
| св. 1·10-2 до 0,1 вкл. | 4 | |
| св. 0,1 до 1 вкл. | 3 | |
| св. 1 до 10 вкл. | 2,5 | |
| св. 10 до 20 вкл. | 2,0 | |
| св. 20 до 50 вкл. | 1,0 | |
| св. 50 до 70 вкл. | 0,5 | |
| св. 70 до 80 | 0,25 | |
|
н-пентан [C5H12]
|
от 1·10-5 до 5·10-5 вкл. | 15 |
| св. 5·10-5 до 1·10-4 вкл. | 10 | |
| св. 1·10-4 до 1·10-3 вкл. | 7 | |
| св. 1·10-3 до 1·10-2 вкл. | 5 | |
| св. 1·10-2 до 0,1 вкл. | 4 | |
| св. 0,1 до 1 вкл. | 3 | |
| св. 1 до 10 вкл. | 2,5 | |
| св. 10 до 20 вкл. | 2,0 | |
| св. 20 до 30 | 1,0 | |
|
ацетилен [C2H2]
|
от 1·10-5 до 5·10-5 вкл. | 15 |
| св. 5·10-5 до 1·10-4 вкл. | 10 | |
| св. 1·10-4 до 1·10-3 вкл. | 7 | |
| св. 1·10-3 до 1·10-2 вкл. | 5 | |
| св. 1·10-2 до 0,1 вкл. | 4 | |
| св. 0,1 до 1 вкл. | 3 | |
| св. 1 до 10 вкл. | 2,5 | |
| св. 10 до 12,5 | 2,0 | |
|
н-гексан [C6H14]
|
от 1·10-5 до 5·10-5 вкл. | 15 |
| св. 5·10-5 до 1·10-4 вкл. | 10 | |
| св. 1·10-4 до 1·10-3 вкл. | 7 | |
| св. 1·10-3 до 1·10-2 вкл. | 5 | |
| св. 1·10-2 до 0,1 вкл. | 4 | |
| св. 0,1 до 1 вкл. | 3 | |
| св. 1 до 7 | 2,5 | |
|
тетрахлорметан (R-10) [CCl4]
|
от 1·10-5 до 5·10-5 вкл. | 15 |
| св. 5·10-5 до 1·10-4 вкл. | 10 | |
| св. 1·10-4 до 1·10-3 вкл. | 7 | |
| св. 1·10-3 до 1·10-2 вкл. | 5 | |
| св. 1·10-2 до 0,1 вкл. | 4 | |
| св. 0,1 до 1 вкл. | 3 | |
| св. 1 до 5 | 2,5 | |
|
вода [H2O]
|
от 5·10-5 до 1·10-4 вкл. | 10 |
| св. 1·10-4 до 1·10-3 вкл. | 7 | |
| св. 1·10-3 до 1·10-2 вкл. | 5 | |
| св. 1·10-2 до 0,1 вкл. | 4 | |
| св. 0,1 до 0,5 | 4 |
* – численно равны границам относительной погрешности при доверительной вероятности P=0,95.
| Интервал номинальных значений молярной доли определяемых компонентов СО, % | Пределы допускаемого относительного отклонения ±Д, % |
| от 1·10-5 до 5·10-5 вкл. | 100 |
| св. 5·10-5 до 1·10-3 вкл. | 50 |
| св. 1·10-3 до 1·10-2 вкл. | 30 |
| св. 1·10-2 до 0,1 вкл. | 20 |
| св. 0,1 до 1 вкл. | 15 |
| св. 1 до 20 вкл. | 10 |
| св. 20 до 70 вкл. | 5 |
| св. 70 до 90 вкл. | 3 |
| св. 90 до 99 вкл. | 0,5 |
| св. 99 до 99,9 | 0,1 |